Date of Award

2011

Publisher

North Dakota State University

Document Type

Dissertation

Degree Awarded

Doctor of Philosophy (PhD)

Program

Civil Engineering

Department

Civil and Environmental Engineering

College

Engineering

Faculty Advisor

Casey, Francis

Description

The objectives of the study were to investigate the sorption and degradation of a glucuronide conjugated natural hormone, 17β-estradio1-3-glucuronide (E2-3G), and its estrogenic metabolites in soil-water systems. Radiolabeled E2-3G was first synthesized in the laboratory. Soil-water batch experiments were then conducted using natural and sterilized topsoil (0-6 cm) and subsoil (18-24 cm) with the radiolabeled E2-3G to investigate the effects of soil organic matter content and microbial activity. The aqueous dissipation of 14C in the batch experiments followed a biphasic pattern with an initial rapid dissipation phase followed by a second slower phase. Significant differences in total aqueous 14C dissipation were observed for the different initial concentrations for both soils, with greater persistence of intact E2-3G at higher initial concentrations.

Rights

NDSU Policy 190.6.2

Handle Identifier

https://hdl.handle.net/10365/29317

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