Date of Award

2014

Publisher

North Dakota State University

Document Type

Thesis

Degree Awarded

Master of Science (MS)

Program

Mechanical Engineering

Department

Mechanical Engineering

College

Engineering

Faculty Advisor

Krishnan, Sumathy

Description

This thesis presents two models of a dye-sensitized solar cell (DSC): diffusion model and electrical model. The main purpose is to investigate interfacial charge transfer and charge transport within the semiconductor/electrolyte layer under illuminated conditions. These two interrelated models confirm that diffusion is the major driving force for electron and ion transport, while the drift of electrons is negligible. The diffusion model was utilized to simulate the temperature influence on the overall efficiency of DSC with a consideration of the voltage loss at titanium dioxide (TiO2)/ transparent conductive oxide (TCO) interface. It reveals that low temperature conditions have serious detrimental effects on the DSCs' performance. Further the electrical model was used to analyze the effect of diffusion/drift, dye loading, and electrode thickness on DSC performance. The predicted optimal electrode thickness ranges between 10-15 μm which is consistent with the thickness (10 μm) used in experimental studies published in the literature.

Rights

NDSU Policy 190.6.2

Rights Link

https://www.ndsu.edu/fileadmin/policy/190.pdf

Handle Identifier

https://hdl.handle.net/10365/27177

Download

Share

COinS